MARIPOSA COUNTY AIR POLLUTION CONTROL DISTRICT

HEXAVALENT CHROMIUM TOXIC CONTROL MEASURE CHROME PLATING
AND CHROMIC ACID ANODIZING OPERATIONS

RULE 901

A. DEFINITIONS: The following definitions shall apply for the purposes of this rule:

AMPERE-HOURS: The integral of electric current applied to a plating tank (amperes) over a period of time (hours).

ANTI-MIST ADDITIVES: A chemical which reduces the emission rate from the tank when added to and maintained in the plating tank.

CHROME: Metallic chrome.

CHROME PLATING: Either hard or decorative.

CHROMIC ACID: An aqueous solution of chromium trioxide (CrO3) or a commercial solution containing chromic acid (H2CrO4), dichromic acid (H2Cr2O7) or trichromic acid (H2Cr3O10).

CHROMIC ACID ANODIZING: The electrolytic process by which a metal surface is converted to an oxide surface coating in a solution containing chromic acid.

CHROMIUM: HEXAVALENT chromium (Cr+6).

CONTROL EQUIPMENT: Any device which reduces emissions from the emissions collection system.

DECORATIVE CHROME PLATING: The process by which chromium is electrodeposited from a solution containing compounds of chromium onto an object resulting in a chrome later 1 micron (0.04 mil) thick or less.

EMISSION FACTOR: The mass of chromium emitted during a test conducted in the emissions collection system in accordance with Air Resources Board Test Method 425 divided by the ampere-hours consumed by the tanks in the tested emissions collection system expressed as the mass of chromium emitted per ampere-hours of electrical current consumed.

EMISSIONS COLLECTION SYSTEM: A device or apparatus used to gather chromium emissions from the surface of a chrome plating or chromic acid anodizing tank or tanks.

FACILITY: A business or businesses engaged in chrome plating or chromic acid anodizing which are owned or operated by the same person or persons and are located on the same parcel or on contiguous parcels.

FACILITYWIDE EMISSIONS FROM HARD CHROME PLATING OR CHROMIC ACID ANODIZING: The total emissions from all hard chrome plating or chromic acid anodizing at the facility over a calendar year. Emissions shall be calculated as the sum of emissions from the emissions collection system at the facility. The emissions from an emissions collection system shall by calculated by multiplying the emission factor for that emissions collection system by the sum of ampere-hours consumed during that year for all of the tanks served by the emissions collection system.

HARD CHROME PLATING: The process by which chromium is electrodeposited from a solution containing compounds of chromium onto an object resulting in a chrome layer thicker than 1 micron (0.04 mil).

PLATING TANK: Any container used to hold a chromium of chromic acid solution for the purposes of chrome plating or chromic acid anodizing.

UNCONTROLLED CHROMIUM EMISSIONS FROM THE HARD CHROME PLATING OR CHROMIC ACID ANODIZING FACILITY: The Chromium emission from the emissions collection system at the facility calculated as if no control equipment is in use. For the purpose of determining compliance with this rule the uncontrolled chromium emissions shall by calculated using an emission factor based on tests conducted in accordance with Air Resources Board Test Method 425 or 14 mg/ampere-hours whichever is less.

B. REQUIREMENTS FOR DECORATIVE CHROME PLATING FACILITIES

  1. No person shall operate a decorative chrome plating tank unless an anti-mist additive is continuously maintained in the plating tank or control equipment is installed and used, in a manner which has been demonstrated to and approved by the Air Pollution Control Officer as reducing chromium emissions by 95 percent or more relative to chromium emissions when an anti-mist additive is not maintained or control equipment is not installed and used.

C. REQUIREMENT FOR HARD CHROME PLATING AND CHROMIC ACID ANODIZING FACILITIES.

  1. The owners or operators of all hard chrome plating and chromic acid anodizing facilities shall maintain a continuous record of current integrated over time (ampere-hours) for all plating tanks for each collection system used in the hard chrome plating or chromic acid anodizing operations and shall within six months after adoption of the Rules enacting this control measure and upon request thereafter, submit the information to the Air Pollution Control Officer.
  2. No person shall operate a plating tank for hard chrome plating or chromic acid anodizing unless the tank has an emissions collection system.
  3. No person shall operate a hard chrome plating or chromic acid anodizing tank unless:
    1. The chromium emissions from the emissions collection system serving the plating tank have been reduced by 95 percent or more of the uncontrolled chromium emissions or ;
    2. The chromium emissions from the emissions collection system serving the plating tank have been reduced to less than 0.15 milligrams (mg) of chromium per ampere-hour of electrical charge applied to the plating tank.
  4. No person shall operate a hard chrome plating tank or chromic acid anodizing tank at a facility if facilitywide chromium emissions from hard chrome plating or chromic acid anodizing are greater than 2 pounds per year but less than 10 pounds per year, unless:
    1. The chromium emissions from the emissions collection system serving the plating tanks have been reduced by at least 99 percent of the uncontrolled chromium emissions from the hard chrome plating or chromic acid anodizing facility or;
    2. The chromium emissions from the emissions collection system are reduced to less than 0.03 milligrams (mg) of chromium per ampere-hour of electrical charge applied to the tanks.
  5. No person shall operate a hard chrome plating or chromic acid anodizing tank at a facility if the facilitywide chromium emissions from hard chrome plating or chromic acid anodizing are 10 pounds per year or greater, unless:
    1. The chromium emissions from the emissions collection system serving the plating tanks have been reduced by at least 99.8 percent of the uncontrolled chromium emissions from the hard chrome plating or chromic acid anodizing facility or;
    2. The chromium emission from the emissions collection system are reduced to less than 0.006 milligrams (mg) of chromium per ampere-hour electrical charge applied to the tanks.

D. COMPLIANCE SCHEDULE - DECORATIVE CHROME PLATING, HARD CHROME PLATING, AND CHROMIC ACID ANODIZING FACILITIES

  1. No later than one month after the adoption of the rules enacting this control measure, the owners or operators of facilities listed above shall submit an application for an Authority to Construct to the Air Pollution Control Officer and comply with the rules enacting this control measure with six months.
  2. Owners or operators of any new facilities listed above shall submit to the Air Pollution Control Officer an application for an Authority to Construct and comply with the rules enacting this control measure prior to the start of business.