SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT
RULE 1125 - METAL CONTAINER, CLOSURE, AND COIL COATING OPERATIONS
(Adopted April 6, 1979)(Amended January 8, 1982)(Amended December 7, 1984) (Amended January 10, 1986)(Amended
May 5, 1989)(Amended December 1, 1989) (Amended March 2, 1990)(Amended November 2, 1990)(Amended December 7, 1990)
(Amended August 2, 1991)(Amended January 13, 1995)
(a) Applicability
This rule applies to all coating operations in the manufacturing and/or reconditioning of metal cans, drums, pails, lids, and closures. It also includes coating of the surface of flat metal sheets, strips, rolls, or coils during the manufacturing and/or reconditioning of metal containers, closures, and coils.
(b) Definitions
For the purpose of this rule, the following definitions shall apply:
(A) Group I (General)
--trifluoromethane (HFC-23)
--pentafluoroethane (HFC-125)
--1,1,2,2-tetrafluoroethane (HFC-134)
--tetrafluoroethane (HFC-134a)
--1,1,1-trifluoroethane (HFC-143a)
--1,1-difluoroethane (HFC-152a)
--chlorodifluoromethane (HCFC-22)
--dichlorotrifluoroethane (HCFC-123)
--2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124)
--dichlorofluoroethane (HCFC-141b)
--chlorodifluoroethane (HCFC-142b)
--cyclic branched, or linear, completely fluorinated alkanes
--cyclic branched, or linear, completely fluorinated ethers with no unsaturations
--cyclic, branched, or linear, completely fluorinated tertiary amines with no unsaturations
--sulfur-containing perfluorocarbons with no unsaturations and with sulfur bonds only to carbon and fluorine
(B) Group II
--methylene chloride
--1,1,1-trichloroethane (methyl chloroform)
--trichlorotrifluoroethane (CFC-113)
--dichlorodifluoromethane (CFC-12)
--trichlorofluoromethane (CFC-11)
--dichlorotetrafluoroethane (CFC-114)
--chloropentafluoroethane (CFC-115)
The use of Group II compounds and/or carbon tetrachloride may be restricted in the future because they are toxic, potentially toxic, upper-atmosphere ozone depleters, or cause other environmental impacts. By January 1, 1996, production of chlorofluorocarbons (CFC), 1,1,1-trichloroethane (methyl chloroform), and carbon tetrachloride will be phased out in accordance with the Code of Federal Regulations Title 40, Part 82 (December 10, 1993).
Grams of VOC per Liter of Coating, Ws - Ww - Wes
Less Water and Less Exempt Compounds = -----------------------
Vm - Vw - Ves
Where:
Ws = weight of volatile compounds in grams
Ww = weight of water in grams
Wes = weight of exempt compounds in grams
Vm = volume of material in liters
Vw = volume of water in liters
Ves = volume of exempt compounds in liters
(c) Requirements
| COATING | VOC LIMITS Grams per Liter of Coating, Less Water and Less Exempt Compounds |
|
| g/L | lb/gal | |
| ------------------------------------------------------------------------- | ||
| Can Coating | ||
| (A) Three-Piece Can Sheet Basecoat (exterior and interior and overvarnish) |
225 | 1.9 |
| (B) Two-Piece Can Exterior Basecoat and Overvarnish |
250 | 2.1 |
| (C) Inks | 300 | 2.5 |
| (D) Can Interior Body Spray | ||
| (i) Two-Piece Can | 440 | 3.7 |
| (ii) Three-Piece Can | 510 | 4.2 |
| (E) Three-Piece Can Side Seam Spray | 660 | 5.5 |
| (F) End Sealing Compound | ||
| (i) Food/Beverage Cans | 440 | 3.7 |
| (ii) Non-Food Cans | 440 | 3.7 |
| (After March 1, 1991) | 0 | 0 |
| (G) Drums, Pails, and Lids Coating | ||
| (i) New | ||
| Exterior | 340 | 2.8 |
| Interior | 420 | 3.5 |
| (ii) Reconditioned | ||
| Exterior | 420 | 3.5 |
| Interior | 510 | 4.2 |
| (H) Necker Lubricants | 100 | 0.8 |
| Coil Coating | 200 | 1.7 |
(A) The emission control system shall collect at least 90 percent by weight of the emissions generated using USEPA, ARB, and District methods specified in subparagraph (e)(2)(A) and have a destruction efficiency of at least 95 percent by weight, or
(B) The approved system shall reduce the VOC emissions when using non-compliant coatings to an equivalent or greater level that would be achieved by the provisions in paragraph (c)(1). The required efficiency of an emission control system at which an equivalent or greater level of VOC reduction will be achieved shall be calculated by the following equation:
(VOCLWc) 1 - (VOCLWn Max/Dn Max)
C.E. = [ 1 - { ------------- X ----------------------- } ] X 100
(VOCLWn Max) 1 - (VOCLWc/Dc)
Where:
C.E. = Control Efficiency, percent VOCLWc = VOC Limit of Rule 1125, less water and less exempt compounds, pursuant to subdivision (c). VOCLWn Max = Maximum VOC content of non-compliant coating used in conjunction with a control device, less water and less exempt compounds. Dn Max = Density of solvent, reducer, or thinner contained in the non-compliant coating, containing the maximum VOC content of the multicomponent coating. Dc = Density of corresponding solvent, reducer, or thinner used in the compliant coating system = 880g/L.
Owners and/or operators may comply with the provisions of paragraph (c)(1) by means of an Alternative Emission Control Plan pursuant to Rule 108.
A person or facility shall not apply any coating subject to the provisions of this rule unless the coating is applied with properly operating equipment according to operating procedures specified by the equipment manufacturer or the Executive Officer or his designee, and by the use of one of the following methods:
(A) electrostatic application; or
(B) flow coat; or
(C) roll coat; or
(D) dip coat; or
(E) high-volume, low-pressure (HVLP) spray; or
(F) hand application methods; or
(G) such other coating application methods as are demonstrated to the Executive Officer to be capable of achieving at least 65 percent transfer efficiency and for which written approval of the Executive Officer has been obtained.
All solvent cleaning operations and the storage and disposal of VOC-containing materials used in solvent cleaning operations shall be carried out pursuant to Rule 1171 - Solvent Cleaning Operations.
Notwithstanding provisions of subdivision (g), records shall be maintained pursuant to Rule 109, except that usage records for complying inks may be grouped by ink categories and each category constitutes a different VOC content.
(d) Prohibition of Specification and Sale
methylene chloride,
trifluoromethane (FC-23),
trichlorotrifluoroethane (CFC-113),
dichlorodifluoromethane (CFC-12),
trichlorofluoromethane (CFC-11),
dichlorotetrafluoroethane (CFC-114), and
chloropentafluoroethane (CFC-115).
(e) Test Methods
(A) United States Environmental Protection Agency (USEPA) Reference Method 24 (Code of Federal Regulations Title 40 Part 60, Appendix A,). The exempt compound content shall be determined by SCAQMD Method 303 (Determination of Exempt Compounds) contained in the SCAQMD "Laboratory Methods of Analysis for Enforcement Samples" manual; or,
(B) SCAQMD Method 304 [Determination of Volatile Organic Compounds (VOC) in Various Materials] contained in the SCAQMD "Laboratory Methods of Analysis for Enforcement Samples" manual.
(C) Exempt Perfluorocarbon Compounds
The following classes of compounds:
--cyclic, branched, or linear, completely fluorinated alkanes;
--cyclic, branched, or linear, completely fluorinated ethers with no unsaturations;
--cyclic, branched, or linear, completely fluorinated tertiary amines with no unsaturations; and
--sulfur-containing perfluorocarbons with no unsaturations and with sulfur bonds only to carbon and fluorine,
will be analyzed as exempt compounds for compliance with subdivision (c), only when manufacturers specify which individual compounds are used in the coating formulation. In addition, the manufacturers must identify the USEPA, California Air Resources Board, and the SCAQMD approved test methods used to quantify the amount of each exempt compound.
(A) The efficiency of the collection device of the emission control system as specified in paragraph (c)(2) shall be determined by the USEPA method cited in 55 Federal Register 26865 (June 29, 1990), or any other method approved by the USEPA, the California Air Resources Board, and the SCAQMD.
(B) The efficiency of the control device of the emission control system as specified in paragraph (c)(2) and the VOC content in the control device exhaust gases, measured and calculated as carbon, shall be determined by USEPA Test Methods 25, 25A, or SCAQMD Test Method 25.1 (Determination of Total Gaseous Non-Methane Organic Emissions as Carbon) as applicable. USEPA Test Method 18, or ARB Method 422 shall be used to determine emissions of exempt compounds.
When more than one test method or set of test methods are specified for any testing, a violation of any requirement of this rule established by any one of the specified test methods or set of test methods shall constitute a violation of this rule.
(f) Rule 442 Applicability
Any metal container, closure, or coil coating operation or facility which is exempt from all or a portion of this rule shall comply with the provisions of Rule 442.
(g) Exemptions